Crystalline Polyphenylene Covalent Organic Frameworks

作者：Xing Han, Zihui Zhou, Kaiyu Wang, Zhiling Zheng, Silvio Neumann, Heyang Zhang, Tianqiong Ma, Omar M. Yaghi · 发表于：Journal of the American Chemical Society · 年份：2023 · DOI：10.1021/jacs.3c11688 · 被引用次数：75 · 研究领域：Covalent Organic Framework Applications、Metal-Organic Frameworks: Synthesis and Applications、Luminescence and Fluorescent Materials

The synthesis of crystalline polyphenylene covalent organic frameworks (COFs) was accomplished by linking fluorinated tris(4-acetylphenyl)benzene building units using aldol cyclotrimerization. The structures of the two COFs, reported here, were confirmed by powder X-ray diffraction techniques, Fourier transform infrared, and solid-state 13 C CP/MAS NMR spectroscopy. The results showed that the COFs were porous and chemically stable in corrosive, harsh environments for at least 1 week. Accordingly, postsynthetically modified derivatives of these COFs using primary amines showed CO 2 uptake from air and flue gas.