Unified and green oxidation of amides and aldehydes for the Hofmann and Curtius rearrangements

作者：Liyan Song, Yufei Meng, Tongchao Zhao, Lifang Liu, Xiaohong Pan, Binbin Huang, Hongliang Yao, Ran Lin, Rongbiao Tong · 发表于：Green Chemistry · 年份：2023 · DOI：10.1039/d3gc04355j · 被引用次数：24 · 研究领域：Chemical Synthesis and Reactions、Oxidative Organic Chemistry Reactions、Chemical Synthesis and Analysis

The oxone–halide green oxidation system is extended to the oxidation of primary amides and aromatic aldehydes (with sodium azide) to generate N -haloamide and acyl azides, respectively, for subsequent Hofmann and Curtius rearrangements.