Visible-light-driven selective difluoroalkylation of α-CF 3 alkenes to access CF 2 -containing gem -difluoroalkenes and trifluoromethylalkanes

作者：Panpan Lei, Bingran Chen, Tonghui Zhang, Qinlin Chen, Liangming Xuan, Haifeng Wang, Qiongjiao Yan, Wei Wang, Jie Zeng, Fen‐Er Chen · 发表于：Organic Chemistry Frontiers · 年份：2023 · DOI：10.1039/d3qo01551c · 被引用次数：28 · 研究领域：Fluorine in Organic Chemistry、Inorganic Fluorides and Related Compounds

A visible-light-mediated selective difluoroalkylation of α-trifluoromethyl alkenes with difluoroalkylating reagents was developed. This protocol allowed the formation of gem -difluoroalkene difluoroacetates and trifluoromethylated difluoroacetamides.