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Ru nanoclusters anchored on boron- and nitrogen-doped carbon for a highly efficient hydrogen evolution reaction in alkaline seawater

作者:Binbin Jiang, Zhen Wang, Hui Zhao, Xie Wang, Xiaoxia Mao, Aijian Huang, Xuehua Zhou, Kui Yin, Kefa Sheng, Junwei Wang · 发表于:Nanoscale · 年份:2023 · DOI:10.1039/d3nr05052a · 被引用次数:13 · 研究领域:Electrocatalysts for Energy Conversion、Advanced battery technologies research、Advanced Photocatalysis Techniques

at an overpotential of 150 mV, which is higher than those of Ru/NC, Ru/BC and Ru/C, respectively. Density functional theory calculation results demonstrate that the Ru-B formed interfacial chemical bond can regulate the electronic structure of Ru active sites of Ru/NBC, which can facilitate the adsorption of water and hydrogen in alkaline media. This work provides a feasible strategy to fabricate outstanding electrocatalysts for the HER in alkaline/alkaline seawater electrolytes.