Cross‐Linked Binary Polymeric Binder of Polyacrylic Acid–Carboxymethyl Cellulose for Improving Phosphorus Anode

作者：Muyao Han, Liang Xu, Chengyu Han, Chaoyi Zhou, Qianxin Xiang, Yu Cao, Jie Sun · 发表于：Advanced Functional Materials · 年份：2023 · DOI：10.1002/adfm.202308325 · 被引用次数：35 · 研究领域：Advancements in Battery Materials、Advanced Battery Materials and Technologies、Supercapacitor Materials and Fabrication

Abstract Phosphorus (P) is a promising anode material with high capacity (2596 mAh g −1 and 6075–6924 mAh cm −3 ), low lithium‐ion diffusion barrier (0.08 eV), and appropriate lithiation potential (≈0.7 V vs Li + /Li). However, the problems of huge volume expansion (≈300%), low electronic conductivity (10 −14 –10 2 S cm −1 ), and soluble intermediates (lithium polyphosphides, Li x pPs) restrict its performance. In this work, a robust, cross‐linked binary polymeric binder polyacrylic acid–carboxymethyl cellulose (PAA/CMC) binder is designed, which has good Li + conductivity and is not reactive with lithium polyphpsphode (Li x pPs). The resulting composite P/CNT‐PAA/CMC displays a high reversible capacity of 1230.2 mAh g −1 after 200 cycles at 1300 mA g −1 , achieving 10 times as much as the control sample P/CNT‐PVDF. The volume expansion after lithiation of P/CNT‐PAA/CMC is only 6%, far less than that of the control sample (83%).