Palladium‐Catalyzed Enantioselective Indole Allylic Alkylation with Chiral Phosphoramidite‐Selenide‐Based Ligands

作者：Bin Feng, Yun‐Fan Zhang, Shan Li, Ge‐Yun You, Jun Xuan · 发表于：European Journal of Organic Chemistry · 年份：2023 · DOI：10.1002/ejoc.202300861 · 被引用次数：6 · 研究领域：Asymmetric Synthesis and Catalysis、Catalytic C–H Functionalization Methods、Asymmetric Hydrogenation and Catalysis

Abstract Environmental Engineering Organic Hybrid Functionalized Materials A Pd/phosphoramidite‐selenide‐catalyzed highly enantioselective C‐3 allylic alkylation with a wide range of indole nucleophiles has been developed, giving the corresponding products with up to 95 % yield and 99 % ee.