Multifunctional Electrolyte toward Long‐Life Zinc‐Ion Batteries: Synchronous Regulation of Solvation, Cathode and Anode Interfaces

作者：Bin Xie, Qiang Hu, Xiangyue Liao, Xiaoqin Zhang, Haoran Lang, Ruyi Zhao, Qiaoji Zheng, Yu Huo, Jingxin Zhao, Dunmin Lin, Xing‐Long Wu · 发表于：Advanced Functional Materials · 年份：2023 · DOI：10.1002/adfm.202311961 · 被引用次数：58 · 研究领域：Advanced battery technologies research、Electrocatalysts for Energy Conversion、Supercapacitor Materials and Fabrication

Abstract Rechargeable aqueous zinc‐ion batteries (ZIBs) are threatened by the cathode dissolution and anode corrosion/dendrites, resulting in poor reversibility. Here, a multifunctional electrolyte is developed to regulate the cathode, anode interface, and solvation by introducing a low‐cost diethylene glycol monomethyl ether (DGME). The DGME can modulate the primary solvation sheath (PSS) of the hydrated Zn 2+ and destroy the original hydrogen bond network of water, while the electric double layer (EDL) interface is reconstructed by the adsorption of DGME, which guides the uniform deposition of Zn 2+ on the (002) crystal plane. Simultaneously, the DGME also effectively inhibits the dissolution of VO 2 and enhances the reaction kinetics. As a proof of concept, the Zn//Cu cells deliver 2000 cycles with an ultrahigh coulombic efficiency (CE) of 99.6%. Additionally, the multifunctional electrolyte significantly improves the multiple performance of Zn//VO 2 full cells. The low‐cost and multifunctional electrolyte can be readily applied to ZIBs, demonstrating its practical versatility.