Mechanical Effects of Elastic Crystals Driven by Natural Sunlight and Force

作者：Jiang Peng, Chuchu Han, Xin Zhang, Junhui Jia, Jiakun Bai, Qi Zhang, Yan Wang, Pengchong Xue · 发表于：Angewandte Chemie International Edition · 年份：2023 · DOI：10.1002/anie.202311348 · 被引用次数：44 · 研究领域：Mechanical and Optical Resonators、Force Microscopy Techniques and Applications

Abstract Flexible crystals that can capture solar energy and convert it into mechanical energy are promising for a wide range of applications such as information storage and actuators, but obtaining them remains a challenge. Herein, an elastic crystal of a barbiturate derivative was found to be an excellent candidate, demonstrating plastic bending behavior under natural sunlight irradiation. 1 H NMR and high‐resolution mass spectrum data of microcrystals before and after light irradiation demonstrated that light‐induced [2+2] cycloaddition was the driving force for the photomechanical effects. Interestingly, the crystals retained elastic bending even after light irradiation. This is the first report of flexible crystals that can be driven by natural sunlight and that have both photomechanical properties and elasticity. Furthermore, regulation of the passive light output direction of the crystals and transport of objects by applying mechanical forces and light was demonstrated.