Occurrence and Fate of Substituted p -Phenylenediamine-Derived Quinones in Hong Kong Wastewater Treatment Plants

作者：Guodong Cao, Wei Wang, Jing Zhang, Pengfei Wu, Han Qiao, Huankai Li, Gefei Huang, Zhu Yang, Zongwei Cai · 发表于：Environmental Science & Technology · 年份：2023 · DOI：10.1021/acs.est.3c03758 · 被引用次数：112 · 研究领域：Pharmaceutical and Antibiotic Environmental Impacts、Water Treatment and Disinfection、Chemical Analysis and Environmental Impact

High Resolution Image Download MS PowerPoint Slide para -Phenylenediamine quinones (PPD-Qs) are a newly discovered class of transformation products derived from para -phenylenediamine (PPD) antioxidants. These compounds are prevalent in runoff, roadside soil, and particulate matter. One compound among these, N -1,3-dimethylbutyl- n ′-phenyl- p -phenylenediamine quinone (6PPD-Q), was found to induce acute mortality of coho salmon, rainbow trout, and brook trout, with the median lethal concentrations even lower than its appearance in the surface and receiving water system. However, there was limited knowledge about the occurrence and fate of these emerging environmental contaminants in wastewater treatment plants (WWTPs), which is crucial for effective pollutant removal via municipal wastewater networks. In the current study, we performed a comprehensive investigation of a suite of PPD-Qs along with their parent compounds across the influent, effluent, and biosolids during each processing unit in four typical WWTPs in Hong Kong. The total concentrations of PPDs and PPD-Qs in the influent were determined to be 2.7–90 and 14–830 ng/L. In the effluent, their concentrations decreased to 0.59–40 and 2.8–140 ng/L, respectively. The median removal efficiency for PPD-Qs varied between 53.0 and 91.0% across the WWTPs, indicating that a considerable proportion of these contaminants may not be fully eliminated through the current processing technology. Mass flow analyses revealed that rel...