Subnanocyclic Molecule of 15-Crown-5 Inhibiting Interfacial Water Decomposition and Stabilizing Zinc Anodes via Regulation of Zn 2+ Solvation Shell

作者：Jiangbin Deng, Haoran Luo, Qianzhi Gou, Jiacheng Wang, Zhaoyu Chen, Nuo Xu, Zixun Liu, Yuting He, Ziga Luogu, Guangming Jiang, Kuan Sun, Yujie Zheng, Meng Li · 发表于：The Journal of Physical Chemistry Letters · 年份：2023 · DOI：10.1021/acs.jpclett.3c01610 · 被引用次数：25 · 研究领域：Advanced battery technologies research、Perovskite Materials and Applications、Advanced Battery Materials and Technologies

Aqueous zinc ion batteries exhibit a promising application prospect for next-generation energy storage devices. However, the decomposition of active H 2 O molecules on the Zn anode induces drastic dendrite formation, thereby impairing the performance for entire devices. To solve this challenge, we introduce subnanocyclic molecules of 15-Crown-5 as an additive into ZnSO 4 electrolyte to stabilize the Zn anode. Owing to the binding property of crown ethers with alkali metal ions and the size-fit rule, the 15-Crown-5 additives enable effective regulation of the solvation structure of hydrated Zn 2+ and reduce the efficient contact between Zn anode and active H 2 O, which are validated by the experimental analysis and theoretical calculations. Under the assistance of the 15-Crown-5 additive, the as-assembled Zn-based batteries deliver superior performance compared with ZnSO 4 and 18-Crown-6contaning ZnSO 4 electrolytes. This work shows a bright direction toward progress in aqueous batteries.