Probing Hidden Mott Gap and Incommensurate Charge Modulation on the Polar Surfaces of PdCrO 2

作者：Chenhaoping Wen, Tian Qin, Xuefeng Zhang, Mingxin Zhang, Weixiong Hu, Shiwei Shen, Zhongzheng Yang, Yanpeng Qi, Gang Li, Shichao Yan · 发表于：Physical Review Letters · 年份：2023 · DOI：10.1103/physrevlett.131.116501 · 被引用次数：6 · 研究领域：Copper-based nanomaterials and applications、ZnO doping and properties、Electronic and Structural Properties of Oxides

Here we report a combined study of low-temperature scanning tunneling microscopy and dynamical mean-field theory on ${\mathrm{PdCrO}}_{2}$, a delafossite metal with an antiferromagnetic order below $\ensuremath{\sim}37.5\text{ }\text{ }\mathrm{K}$. First, on the ${\mathrm{CrO}}_{2}$-terminated polar surface we detect a gaplike feature both below and above the N\'eel temperature. The dynamical mean-field theory calculations indicate that this gap is opened due to the strong correlations of $\mathrm{Cr}\text{\ensuremath{-}}3d$ electrons, suggesting the hidden Mott nature of the gap. Then, we observe two kinds of Pd-terminated polar surfaces. One is a well-ordered Pd surface with the Fermi-surface-nesting-induced incommensurate charge modulation, while the other one is a reconstructed Pd surface with the individual nanoscale nonperiodic domain structures. On the well-ordered Pd surface, the interference between the incommensurate charge modulation and the atomic lattice forms the periodic moir\'e pattern. Our results provide important microscopic information for fully understanding the correlated electronic properties of this class of materials.