Room temperature stable E , Z -diphosphenes: their isomerization, coordination, and cycloaddition chemistry

作者：Jieli Lin, Zhongshu Li, Jie Zhang, Hansjörg Grützmacher, Cheng‐Yong Su, Zhongshu Li · 发表于：Chemical Science · 年份：2023 · DOI：10.1039/d3sc04506d · 被引用次数：8 · 研究领域：Synthesis and characterization of novel inorganic/organometallic compounds、Organometallic Complex Synthesis and Catalysis、Coordination Chemistry and Organometallics

N-Heterocyclic vinyl substituted diphosphenes 2b in both E - and Z -isomers have been isolated and crystallographically characterized. They exhibit reversible photo- and thermally stimulated E ↔ Z isomerization mimicking their carbon analogue.