Doping engineering of lithium-aluminum layered double hydroxides for high-efficiency lithium extraction from salt lake brines

作者：Lingjie Zhang, Tingting Zhang, Yunliang Zhao, Guangfeng Dong, Shuaike Lv, Songliang Ma, Shaoxian Song, Mildred Quintana · 发表于：Nano Research · 年份：2023 · DOI：10.1007/s12274-023-5950-1 · 被引用次数：152 · 研究领域：Layered Double Hydroxides Synthesis and Applications、Advanced Battery Materials and Technologies、Extraction and Separation Processes

Lithium-aluminum layered double hydroxides (LiAl-LDH) have been be successfully applied in commercial-scale for lithium extraction from salt lake brine, however, further advancement of their applications is hampered by suboptimal Li+ adsorption performance and ambiguous extraction process. Herein, a doping engineering strategy was developed to fabricate novel Zn 2+ -doped LiAl-LDH (LiZnAl-LDH) with remarkable higher Li + adsorption capacity (13.4 mg/g) and selectivity (separation factors of 213, 834, 171 for Li + /K + , Li + /Na + , Li + /Mg 2+ , respectively), as well as lossless reusability in Luobupo brine compared to the pristine LiAl-LDH. Further, combining experiments and simulation calculations, it was revealed that the specific surface area, hydrophilic, and surface attraction for Li + of LiZnAl-LDH were significantly improved, reducing the adsorption energy ( E ad ) and Gibbs free energy (ΔG), thus facilitating the transfer of Li + from brine into interface followed by insertion into voids. Importantly, the intrinsic oxygen vacancies derived from Zn-doping depressed the diffusion energy barrier of Li + , which accelerated the diffusion process of Li + in the internal bulk of LiZnAl-LDH. This work provides a general strategy to overcome the existing limitations of Li + recovery and deepens the understanding of Li + extraction on LiAl-LDH.