Vanadium-catalysed regioselective hydroboration of epoxides for synthesis of secondary alcohols

作者：Guoqi Zhang, Haisu Zeng, Quan Tang, Selin Ates, Shengping Zheng, Michelle C. Neary · 发表于：Dalton Transactions · 年份：2023 · DOI：10.1039/d3dt01865b · 被引用次数：8 · 研究领域：Chemical Synthesis and Reactions、Asymmetric Hydrogenation and Catalysis、Organoboron and organosilicon chemistry

A facile epoxide ring-opening hydroboration reaction catalysed by an active vanadium complex supported by a redox-active terpyridine ligand is reported for the synthesis of secondary alcohols under mild conditions.