Transition Metal‐Catalyzed Enantioselective Synthesis of Chiral Five‐ and Six‐Membered Benzo O ‐heterocycles

作者：Yang Lu, Xiayu Liang, Yuyang Ding, Xinran Li, Xuefeng Li, Qingle Zeng · 发表于：The Chemical Record · 年份：2023 · DOI：10.1002/tcr.202300173 · 被引用次数：9 · 研究领域：Asymmetric Synthesis and Catalysis、Catalytic C–H Functionalization Methods、Asymmetric Hydrogenation and Catalysis

Enantiomerically enriched five- and six-membered benzo oxygen heterocycles are privileged architectures in functional organic molecules. Over the last several years, many effective methods have been established to access these compounds. However, comprehensive documents cover updated methodologies still in highly demand. In this review, recent transition metal catalyzed transformations lead to chiral five- and six-membered benzo oxygen heterocycles are presented. The mechanism and chirality transfer or control processes are also discussed in details.