Highly Selective Electrochemical Nitrate to Ammonia Conversion by Dispersed Ru in a Multielement Alloy Catalyst

作者：Meiqi Yang, Boyang Li, Shuke Li, Qi Zhi Dong, Zhennan Huang, Sunxiang Sean Zheng, Ying Fang, Guangye Zhou, Xi Chen, Xiaobo Zhu, Tangyuan Li, Miaofang Chi, Guofeng Wang, Liangbing Hu, Zhiyong Jason Ren · 发表于：Nano Letters · 年份：2023 · DOI：10.1021/acs.nanolett.3c01978 · 被引用次数：77 · 研究领域：Ammonia Synthesis and Nitrogen Reduction、Advanced Photocatalysis Techniques、Nanomaterials for catalytic reactions

Electrochemical reduction of nitrate to ammonia (NH 3 ) converts an environmental pollutant to a critical nutrient. However, current electrochemical nitrate reduction operations based on monometallic and bimetallic catalysts are limited in NH 3 selectivity and catalyst stability, especially in acidic environments. Meanwhile, catalysts with dispersed active sites generally exhibit a higher atomic utilization and distinct activity. Herein, we report a multielement alloy nanoparticle catalyst with dispersed Ru (Ru-MEA) with other synergistic components (Cu, Pd, Pt). Density functional theory elucidated the synergy effect of Ru-MEA than Ru, where a better reactivity (NH 3 partial current density of −50.8 mA cm –2 ) and high NH 3 faradaic efficiency (93.5%) is achieved in industrially relevant acidic wastewater. In addition, the Ru-MEA catalyst showed good stability (e.g., 19.0% decay in FE NH3 in three hours). This work provides a potential systematic and efficient catalyst discovery process that integrates a data-guided catalyst design and novel catalyst synthesis for a range of applications.