Integrated halide perovskite photoelectrochemical cells with solar-driven water-splitting efficiency of 20.8%

作者：Austin M. K. Fehr, Ayush Agrawal, Faiz Mandani, Christian L. Conrad, Qi Jiang, So Yeon Park, Olivia J. Alley, Bor Li, Siraj Sidhik, Isaac Metcalf, Christopher Botello, James L. Young, Jacky Even, Jean‐Christophe Blancon, Todd Gregory Deutsch, Kai Zhu, Steve Albrecht, Francesca Maria Toma, Michael S. Wong, Aditya D. Mohite · 发表于：Nature Communications · 年份：2023 · DOI：10.1038/s41467-023-39290-y · 被引用次数：167 · 研究领域：Perovskite Materials and Applications、Electrocatalysts for Energy Conversion、Advanced Photocatalysis Techniques

Abstract Achieving high solar-to-hydrogen (STH) efficiency concomitant with long-term durability using low-cost, scalable photo-absorbers is a long-standing challenge. Here we report the design and fabrication of a conductive adhesive-barrier (CAB) that translates >99% of photoelectric power to chemical reactions. The CAB enables halide perovskite-based photoelectrochemical cells with two different architectures that exhibit record STH efficiencies. The first, a co-planar photocathode-photoanode architecture, achieved an STH efficiency of 13.4% and 16.3 h to t60, solely limited by the hygroscopic hole transport layer in the n-i-p device. The second was formed using a monolithic stacked silicon-perovskite tandem, with a peak STH efficiency of 20.8% and 102 h of continuous operation before t60 under AM 1.5G illumination. These advances will lead to efficient, durable, and low-cost solar-driven water-splitting technology with multifunctional barriers.