Stereoselective alkyl C -glycosylation of glycosyl esters via anomeric C–O bond homolysis: efficient access to C -glycosyl amino acids and C -glycosyl peptides

作者：Anrong Chen, Shiyin Zhao, Yang Han, Zhenghong Zhou, Bo Yang, Lan‐Gui Xie, Maciej A. Walczak, Feng Zhu · 发表于：Chemical Science · 年份：2023 · DOI：10.1039/d3sc01995k · 被引用次数：65 · 研究领域：Carbohydrate Chemistry and Synthesis、Chemical Synthesis and Analysis、Radical Photochemical Reactions

A novel photoredox-catalyzed radical conjugate addition of 1,4-dihydropyridine-derived glycosyl esters and dehydroalanine derivatives via anomeric C(sp 3 )–O bond homolysis to construct C -glycosyl amino acids and peptides is for the first time described.