Strategies for Improving the Photocatalytic Hydrogen Evolution Reaction of Carbon Nitride‐Based Catalysts

作者：Xueze Chu, CI Sathish, Jae‐Hun Yang, Xinwei Guan, Xiangwei Zhang, Liang Qiao, Kazunari Domen, Shaobin Wang, Ajayan Vinu, Jiabao Yi · 发表于：Small · 年份：2023 · DOI：10.1002/smll.202302875 · 被引用次数：115 · 研究领域：Advanced Photocatalysis Techniques、Catalytic Processes in Materials Science、Copper-based nanomaterials and applications

Due to the depletion of fossil fuels and their-related environmental issues, sustainable, clean, and renewable energy is urgently needed to replace fossil fuel as the primary energy resource. Hydrogen is considered as one of the cleanest energies. Among the approaches to hydrogen production, photocatalysis is the most sustainable and renewable solar energy technique. Considering the low cost of fabrication, earth abundance, appropriate bandgap, and high performance, carbon nitride has attracted extensive attention as the catalyst for photocatalytic hydrogen production in the last two decades. In this review, the carbon nitride-based photocatalytic hydrogen production system, including the catalytic mechanism and the strategies for improving the photocatalytic performance is discussed. According to the photocatalytic processes, the strengthened mechanism of carbon nitride-based catalysts is particularly described in terms of boosting the excitation of electrons and holes, suppressing carriers recombination, and enhancing the utilization efficiency of photon-excited electron-hole. Finally, the current trends related to the screening design of superior photocatalytic hydrogen production systems are outlined, and the development direction of carbon nitride for hydrogen production is clarified.