Cathodic deposition of MOF films: mechanism and applications

作者：Sijie Xie, Zhenyu Zhou, Xuan Zhang, Jan Fransaer · 发表于：Chemical Society Reviews · 年份：2023 · DOI：10.1039/d3cs00131h · 被引用次数：82 · 研究领域：Metal-Organic Frameworks: Synthesis and Applications、Gas Sensing Nanomaterials and Sensors、Catalytic Processes in Materials Science

, simple operations, mild conditions, and controllable MOF film thickness/morphology) over other reported techniques. Accordingly, we discuss the mechanism of the cathodic deposition of MOF films which consists of the electrochemically triggered deprotonation of organic linkers and the formation of inorganic building blocks. Thereafter, the main applications of cathodically deposited MOF films are introduced with the aim of showing this technique's wide-ranging applications. Finally, we give the remaining issues and outlooks of the cathodic deposition of MOF films to drive its future development.