Mechanistic Insights into Photochemical CO 2 Reduction to CH 4 by a Molecular Iron–Porphyrin Catalyst

作者：Jiayi Chen, Man Li, Rong‐Zhen Liao · 发表于：Inorganic Chemistry · 年份：2023 · DOI：10.1021/acs.inorgchem.3c00402 · 被引用次数：22 · 研究领域：CO2 Reduction Techniques and Catalysts、Carbon dioxide utilization in catalysis、Porphyrin and Phthalocyanine Chemistry

Iron tetraphenylporphyrin complex modified with four trimethylammonium groups (Fe- p -TMA) is found to be capable of catalyzing the eight-electron eight-proton reduction of CO 2 to CH 4 photochemically in acetonitrile. In the present work, density functional theory (DFT) calculations have been performed to investigate the reaction mechanism and to rationalize the product selectivity. Our results revealed that the initial catalyst Fe- p -TMA ([Cl–Fe(III)-LR 4 ] 4+, where L = tetraphenylporphyrin ligand with a total charge of −2, and R 4 = four trimethylammonium groups with a total charge of +4) undergoes three reduction steps, accompanied by the dissociation of the chloride ion to form [Fe(II)-L ••2– R 4 ] 2+ . [Fe(II)-L ••2– R 4 ] 2+, bearing a Fe(II) center ferromagnetically coupled with a tetraphenylporphyrin diradical, performs a nucleophilic attack on CO 2 to produce the 1 η-CO 2 adduct [CO 2 •– –Fe(II)-L •– R 4 ] 2+ . Two intermolecular proton transfer steps then take place at the CO 2 moiety of [CO 2 •– –Fe(II)-L •– R 4 ] 2+, resulting in the cleavage of the C–O bond and the formation of the critical intermediate [Fe(II)–CO] 4+ after releasing a water molecule. Subsequently, [Fe(II)–CO] 4+ accepts three electrons and one proton to generate [CHO–Fe(II)-L •– R 4 ] 2+, which finally undergoes a successive four-electron-five-proton reduction to produce methane without forming formaldehyde, methanol, or formate. Notably, the redox non-innocent tetraphenylporphyrin ligand was...