Oxygen vacancy promoted carbon dioxide activation over Cu/ZrO 2 for CO 2 -to-methanol conversion

作者：Haohao Chang, Feifan Gao, Alin Luo, Yongmei Liu, Yifeng Zhu, Heyong He, Yong Cao · 发表于：Chemical Communications · 年份：2023 · DOI：10.1039/d3cc01834b · 被引用次数：36 · 研究领域：Catalytic Processes in Materials Science、Catalysts for Methane Reforming、Catalysis and Oxidation Reactions

Incorporating oxygen vacancies into t-ZrO 2 has shown promise in generating the crucial COOH species through single-electron activation, essential for exceptional low-temperature methanol synthesis via CO 2 hydrogenation over Cu/ZrO 2 catalysts.