Lead-chelating hole-transport layers for efficient and stable perovskite minimodules

作者：Chengbin Fei, Nengxu Li, Mengru Wang, Xiaoming Wang, Hangyu Gu, Bo Chen, Zhao Zhang, Zhenyi Ni, Haoyang Jiao, Wenzhan Xu, Zhifang Shi, Yanfa Yan, Jinsong Huang · 发表于：Science · 年份：2023 · DOI：10.1126/science.ade9463 · 被引用次数：366 · 研究领域：Perovskite Materials and Applications、Solid-state spectroscopy and crystallography、Organic Light-Emitting Diodes Research

The defective bottom interfaces of perovskites and hole-transport layers (HTLs) limit the performance of p-i-n structure perovskite solar cells. We report that the addition of lead chelation molecules into HTLs can strongly interact with lead(II) ion (Pb 2+ ), resulting in a reduced amorphous region in perovskites near HTLs and a passivated perovskite bottom surface. The minimodule with an aperture area of 26.9 square centimeters has a power conversion efficiency (PCE) of 21.8% (stabilized at 21.1%) that is certified by the National Renewable Energy Laboratory (NREL), which corresponds to a minimal small-cell efficiency of 24.6% (stabilized 24.1%) throughout the module area. Small-area cells and large-area minimodules with lead chelation molecules in HTLs had a light soaking stability of 3010 and 2130 hours, respectively, at an efficiency loss of 10% from the initial value under 1-sun illumination and open-circuit voltage conditions.