Design and research of high‐performance electromagnetic interference shielding GO / NiNCs / PMMA microcellular foams

作者：Kai Wang, Chiyu Zhou, Yibo Zhou, Yijia Fan, Junkang Chen, Linghao Hui, Xinyuan Zhang, Jianbin Qin · 发表于：Journal of Applied Polymer Science · 年份：2023 · DOI：10.1002/app.54070 · 被引用次数：10 · 研究领域：Electromagnetic wave absorption materials、Flame retardant materials and properties、Cellular and Composite Structures

Abstract High performance electromagnetic (EM) interference shielding composites are of high demand due to increasing EM wave radiation pollution. In this work, GO/NiNCs/PMMA microcellular foams with different GO/NiNCs gradient and 3D conductive filler framework were fabricated by thermal reduction and supercritical CO 2 foaming process. With the crosslink of 1D NiNCs and 2D GO sheets, GO/NiNCs framework with electrical conductivity varied from 1.15 × 10 −4 to highest 1.09 × 10 −1 S/m is fabricated, exhibiting absorption‐dominated electromagnetic interference shieling effectiveness (EMI SE) of 53.62 dB and specific EMI SE of 48.44 dB g −1 cm 3 in X‐band. The density of GO/NiNCs/PMMA microcellular foams achieved lowest value of 0.623 g/cm 3 . Moreover, the foams showed excellent thermal conductivity and compressive strength of 178.76 MPa, indicating excellent application potential in aerospace and electronic field. The thermoplastic polymer matrix also indicates great potential in recycle of the foam material.