Nanotomography Investigation of 3D Printed Batteries with a Water-in-Salt Gel Polymer Electrolyte

作者：Dean Yen, Cheng-Hung Lin, David Sprouster, Xiaoying Zheng, Xianghui Xiao, Wah-Keat Lee, Mingyuan Ge, Yu‐chen Karen Chen‐Wiegart · 发表于：ACS Materials Letters · 年份：2023 · DOI：10.1021/acsmaterialslett.2c01133 · 被引用次数：9 · 研究领域：Advanced Battery Materials and Technologies、Advancements in Battery Materials、Supercapacitor Materials and Fabrication

3D printing, also known as additive manufacturing, has emerged as a promising strategy to design and fabricate future energy storage devices. Although significant progress has been reported, current 3D printed battery designs are still limited by the choice of the electrolyte, such as ceramic or conventional toxic organic electrolytes. Here, we incorporated the latest developments in aqueous batteries into a novel 3D printable battery that can be fabricated directly in an ambient environment that is also more environmentally friendly. Specifically, a gel polymer electrolyte with a water-in-salt concept was introduced in our 3D-printed batteries. Combining their advantages, the resulting 3D printable batteries show promise for much simplified processing conditions. The structural, (electro-)chemical, and morphological evolution batteries are being investigated by synchrotron X-ray nanotomography and electrochemical analysis. Overall, our research explores the possibility of an easier and more environmentally friendly way to build 3D printable, customizable batteries for future technologies.