Hydride Transfer-Initiated Cross-Dehydrogenative Coupling Reaction to Access Nine-Membered Rings

作者：Xiao‐De An, Da-Ying Shao, Bin Qiu, Jian Xiao · 发表于：Organic Letters · 年份：2023 · DOI：10.1021/acs.orglett.3c00193 · 被引用次数：26 · 研究领域：Catalytic C–H Functionalization Methods、Synthesis and Catalytic Reactions、Catalytic Cross-Coupling Reactions

An unprecedented hydride transfer-triggered cross-dehydrogenative coupling of two C(sp 3 )–H bonds to target nine-membered rings has been developed. Salient features of this methodology include atom and step economy and metal-free and redox-neutral conditions, with water as the byproduct and proceeding well even with decomposed aldehydes.