Weakened d–p orbital hybridization in in situ reconstructed Ru/β-Co(OH) 2 heterointerfaces for accelerated ammonia electrosynthesis from nitrates

作者：Weijie Zhu, Fen Yao, Qiongfei Wu, Qiu Jiang, Jinxian Wang, Zhoucheng Wang, Hanfeng Liang · 发表于：Energy & Environmental Science · 年份：2023 · DOI：10.1039/d3ee00371j · 被引用次数：207 · 研究领域：Ammonia Synthesis and Nitrogen Reduction、Advanced Photocatalysis Techniques、Caching and Content Delivery

Electron-deficient Ru sites at Ru/Co(OH) 2 heterointerfaces weaken the d–p orbital hybridization ability and further facilitate the desorption of ammonia intermediates, thereby achieving ultrahigh nitrate electroreduction activity towards ammonia.