A dense 3d–4f metal–organic framework with “gas pockets” for highly efficient CH 4 /N 2 separation

作者：Li‐Min Zhu, Wenliang Li, Tianran Li, Linping Shi, Liting Li, Zhao‐Quan Yao, Hongliang Huang, Jiong‐Peng Zhao, Fu‐Chen Liu · 发表于：Inorganic Chemistry Frontiers · 年份：2023 · DOI：10.1039/d3qi00235g · 被引用次数：17 · 研究领域：Metal-Organic Frameworks: Synthesis and Applications、Covalent Organic Framework Applications、Inorganic Fluorides and Related Compounds

A pillar-layered dense 3d–4f MOF shows high IAST selectivity for CH 4 /N 2 owing to the enhancement of the interactions between the MOF and CH 4 by the heteroatoms of the pillars.