Synthetic engineering of a new biocatalyst encapsulating [NiFe]-hydrogenases for enhanced hydrogen production

作者：Qiuyao Jiang, Tianpei Li, Jing Yang, Catherine M. Aitchison, Jiafeng Huang, Yu Chen, Fang Huang, Qiang Wang, Andrew I. Cooper, Lu‐Ning Liu · 发表于：Journal of Materials Chemistry B · 年份：2023 · DOI：10.1039/d2tb02781j · 被引用次数：37 · 研究领域：Metalloenzymes and iron-sulfur proteins、Electrocatalysts for Energy Conversion、Catalysis for Biomass Conversion

shows substantially improved hydrogen production under both aerobic and anaerobic conditions and enhanced material and functional robustness, compared to unencapsulated [NiFe]-hydrogenases. The catalytically functional nanoreactor as well as the self-assembling and encapsulation strategies provide a framework for engineering new bioinspired electrocatalysts to improve the sustainable production of fuels and chemicals in biotechnological and chemical applications.