Hydroxyl radical-dominated selective oxidation of ethylbenzene over a photoactive polyoxometalate-based metal–organic framework

作者：Jiachen Jiao, Ting Zhang, Jiangbo Xu, Kaixin Guo, Jie Li, Qiuxia Han · 发表于：Chemical Communications · 年份：2023 · DOI：10.1039/d2cc06403k · 被引用次数：29 · 研究领域：Polyoxometalates: Synthesis and Applications、Metal-Organic Frameworks: Synthesis and Applications、Chemical Synthesis and Reactions

A new photoactive POMOF with a stable structure, suitable band gap and good photoelectric properties was assembled. It exhibits an excellent yield and selectivity for ethylbenzene oxidation with O 2 /H 2 O by precise control of ˙OH formation.