Anisotropic Optical and Mechanical Properties in Few‐Layer GaPS 4

作者：Shuai Liu, Xuwei Cui, Qinghua Zhang, Wanfu Shen, Jiantao Du, Ting Lin, Yunkun Wang, Minghui Wu, Lin Gu, Yunan Gao, Chunguang Hu, Luqi Liu, Shengxue Yang, Chengbao Jiang · 发表于：Advanced Optical Materials · 年份：2023 · DOI：10.1002/adom.202202288 · 被引用次数：13 · 研究领域：2D Materials and Applications、MXene and MAX Phase Materials、Advanced Sensor and Energy Harvesting Materials

Abstract Low‐symmetry 2D materials have received tremendous attention due to their anisotropic optical, electrical, and mechanical properties and viable candidates for polarized photodetectors, anisotropic field‐effect transistors, and nanomechanical systems. Here, an interesting low‐symmetry 2D material (GaPS 4 ) is reported and its in‐plane anisotropic structure, optical, and mechanical properties are investigated. The polarized Raman and absorption spectra prove the sensitivity of GaPS 4 to crystalline orientation and linear dichroism. The experimental results of azimuth‐dependent reflectance difference microscopy can visually reveal the in‐plane optical anisotropy of GaPS 4 flakes. Moreover, an interesting pressurized bubble method is designed to verify the anisotropic mechanical properties of GaPS 4 flakes and saddle‐like bubble devices of GaPS 4 are successfully fabricated. The saddle‐like bubble devices exhibit visual anisotropic deflection variations along the orthogonal direction. Kelvin probe force microscope enables the direct identifying of the surface potential distribution of bubble devices under strain. Interest would be excited in the anisotropic optical and mechanical properties and relevant device applications of low‐symmetry 2D materials.