Photoredox-catalyzed sequential Dowd–Beckwith ring expansion and C–H functionalization of THIQs

作者：Hong Xin, Li‐Na Guo, Mingyu Yang, Cheng Guan, Zi-Hang Yuan, Xin‐Hua Duan · 发表于：Organic Chemistry Frontiers · 年份：2023 · DOI：10.1039/d2qo02001g · 被引用次数：15 · 研究领域：Catalytic C–H Functionalization Methods、Sulfur-Based Synthesis Techniques、Synthesis and Catalytic Reactions

An efficient tandem Dowd–Beckwith ring expansion/C–H functionalization of tetrahydroisoquinoline (THIQ) is disclosed upon photocatalysis, which provided a unique thought to connect important medium-sized cycloalkanones with THIQs skeletons together.