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Thermally activated bipyridyl-based Mn-MOFs with Lewis acid–base bifunctional sites for highly efficient catalytic cycloaddition of CO 2 with epoxides and Knoevenagel condensation reactions

作者:Zhen Xu, Ya‐Yu Zhao, Le Chen, Cai‐Yong Zhu, Peng Li, Wei Gao, Jiyang Li, Xiu‐Mei Zhang · 发表于:Dalton Transactions · 年份:2023 · DOI:10.1039/d3dt00043e · 被引用次数:29 · 研究领域:Metal-Organic Frameworks: Synthesis and Applications、Carbon dioxide utilization in catalysis、Covalent Organic Framework Applications

A bipyridyl-based Mn 2+ -organic framework was synthesized. Activated Mn-MOF- 1 could serve as an efficient heterogeneous catalyst for the cycloaddition of CO 2 with epoxides and Knoevenagel condensation reactions.