Chiral copper-hydride nanoclusters: synthesis, structure, and assembly

作者：Lin Wang, Xiaodan Yan, Guolong Tian, Zhen‐Lang Xie, Shanshan Shi, Yuhao Zhang, Simin Li, Xueli Sun, Jing Sun, Jinlu He, Hui Shen · 发表于：Dalton Transactions · 年份：2023 · DOI：10.1039/d2dt03788b · 被引用次数：28 · 研究领域：Nanocluster Synthesis and Applications、Metal-Organic Frameworks: Synthesis and Applications、Inorganic Chemistry and Materials

, C-H⋯Cu interactions and C-H⋯π interactions) to lock the central copper core. The interlacing of chiral-cluster enantiomers forms a large cavity, which lays the foundation for a series of potential applications such as drug filling and gas adsorption. Moreover, the C-H⋯H-C interactions of phenyl groups between different cluster moieties promote the formation of a dextral helix and realization of the self-assembly of nanostructures.