Graphdiyne‐Based Single‐Atom Catalysts with Different Coordination Environments

作者：Xinliang Fu, Xin Zhao, Tong‐Bu Lu, Mingjian Yuan, Mei Wang · 发表于：Angewandte Chemie International Edition · 年份：2023 · DOI：10.1002/anie.202219242 · 被引用次数：95 · 研究领域：Catalytic Processes in Materials Science、Electrocatalysts for Energy Conversion、Ammonia Synthesis and Nitrogen Reduction

As a special carbon material, graphdiyne (GDY) features the superiorities of incomplete charge transfer effect on the atomic level, tunable electronic structure and anchoring metal atoms directly with organometallic coordination bonds M (metal)-C (alkynyl carbon in GDY), providing it an ideal platform to construct single-atom catalysts (ACs). The coordination environment of single atoms anchored on GDY plays a key role in their catalytic performance. The mini-review highlights state-of-the-art progress in the rational design of GDY-based ACs and their applications, and mainly reveals the relationship between the coordination engineering of the GDY-based ACs and corresponding catalytic performance. Finally, some prospects concerning the future development of GDY-based ACs in energy conversion are also discussed.