Can a heavy trinitromethyl group always result in a higher density?

作者：Ning Ding, Qi Sun, Xudong Xu, Yaqiong Li, Chaofeng Zhao, Shenghua Li, Siping Pang · 发表于：Chemical Communications · 年份：2023 · DOI：10.1039/d2cc07077d · 被引用次数：30 · 研究领域：Energetic Materials and Combustion、Crystallography and molecular interactions、Chemical Reaction Mechanisms

). Mechanistic studies indicated that the reduced density was due to the significantly weaker H-bonding and π-π interactions of TN-116, which produced looser stacking compared to that of LLM-116.