Edge-oriented phosphatizing engineering of 2D Ni-MOFs with a tailored d-band center for boosting catalytic activity

作者：Chongchong Wang, Lulu Kong, Bingbing Chen, Lin Zhou, Wei Wang, Shaohua Wei · 发表于：Nanoscale · 年份：2023 · DOI：10.1039/d2nr06264j · 被引用次数：13 · 研究领域：Nanomaterials for catalytic reactions、MXene and MAX Phase Materials、Advanced Photocatalysis Techniques

P heterostructure, the as-prepared heterostructure showed upregulated d-band center, more robust 4-nitrophenol (4-NP) adsorption capacity, lowered energy barrier of the rate-determining step (RDS), and higher specific surface area, resulting in the best performance of the hydrogenation reduction of 4-NP to 4-aminophenol (4-AP) in the presence of non-precious metal catalysts.