An Organic Redox Mediator with a Defense‐Donor for Lithium Anode in Lithium–Oxygen Batteries

作者：Zongqiang Sun, Yan-Yan Tan, Yingjie Zhan, Kaixuan Li, Wenjie Dou, Chutao Wang, Xiaodong Lin, Ruming Yuan, Jiawei Yan, Mingsen Zheng, Quanfeng Dong · 发表于：Small Methods · 年份：2022 · DOI：10.1002/smtd.202201289 · 被引用次数：22 · 研究领域：Advanced Battery Materials and Technologies、Advancements in Battery Materials、Advanced battery technologies research

Abstract Lithium–oxygen batteries (LOBs) suffer from large charge overpotential and unstable Li metal interface, which can be attributed to the inefficient charge transport at the insulating Li 2 O 2 /cathode interface and the severe oxygen corrosion issue on the Li anode surface. The use of soluble redox mediators (RMs) can effectively enhance the charge transport between Li 2 O 2 and cathode, thus greatly reducing the charge overpotential. However, oxidized RMs will also shuttle to the anode side and react with the Li metal, which not only results in the loss of both the RMs and the electrical energy efficiency but also exacerbates the Li anode corrosion. Herein, an organic compound—acetylthiocholine iodide (ATCI), in which a big cation group is contained, is proposed as a defense‐donor RM for lithium anode in LOBs to simultaneously address the above issues. During charge, it can accelerate the oxidation kinetics of Li 2 O 2 via its iodide anion redox couple (I − /I 3 − ). Meanwhile, its cation segment (ATC + ) can move to the anode surface via electric attraction and in situ forms a protective interfacial layer, which prevents the Li anode from the attack of oxidized RM and oxygen species. Consequently, the ATCI‐containing LOBs can achieve both a low charge potential (≈3.49 V) and a long cycle life (≈190 cycles).