An Efficient Perovskite‐Like Phosphor with Peak Emission Wavelength at 850 nm for High‐Performance NIR LEDs

作者：Wenqiang Tang, Dan Wu, Yu Xiao, Xiaoling Dong, Yue Wang, Wenping Zhou, Yifan Liu, Liangliang Zhang · 发表于：Advanced Optical Materials · 年份：2022 · DOI：10.1002/adom.202202237 · 被引用次数：44 · 研究领域：Luminescence Properties of Advanced Materials、Perovskite Materials and Applications、Advanced Photocatalysis Techniques

Abstract Near‐infrared (NIR) phosphor‐converted light‐emitting diodes (pc‐LEDs) are an emerging light source demanded for the miniaturization of NIR spectroscopy. However, the photoelectric efficiency and spectral properties of NIR pc‐LEDs are still very limited due to a lack of efficient broadband NIR phosphors with peak emission wavelength >850 nm. Here, a novel Cr 3+ ‐activated perovskite‐like Mg 4 Ta 2 O 9 phosphor is reported, which exhibits a broad NIR emission band peaking at 850 nm with a high internal (external) quantum efficiency of 72% (33.4%). The fabricated NIR pc‐LED shows a broad emission band covering the whole 700–1100 nm spectrum range with a photoelectric conversion efficiency of 22.1% at 10 mA. This work may provide a new paradigm for the discovery of Cr 3+ singly doped NIR phosphors with excellent performance.