Identification of the Origin of Ultralow Dark Currents in Organic Photodiodes

作者：Xiao Ma, Haijun Bin, Bas T. van Gorkom, Tom P. A. van der Pol, Matthew Dyson, Christ H. L. Weijtens, Marco Fattori, Stefan C. J. Meskers, Albert J. J. M. van Breemen, Daniel Tordera, René A. J. Janssen, Gerwin H. Gelinck · 发表于：Advanced Materials · 年份：2022 · DOI：10.1002/adma.202209598 · 被引用次数：70 · 研究领域：Organic Electronics and Photovoltaics、Conducting polymers and applications、Perovskite Materials and Applications

Abstract Organic bulk heterojunction photodiodes (OPDs) attract attention for sensing and imaging. Their detectivity is typically limited by a substantial reverse bias dark current density ( J d ). Recently, using thermal admittance or spectral photocurrent measurements, J d has been attributed to thermal charge generation mediated by mid‐gap states. Here, the temperature dependence of J d in state‐of‐the‐art OPDs is reported with J d down to 10 −9 mA cm −2 at −0.5 V bias. For a variety of donor‐acceptor bulk‐heterojunction blends it is found that the thermal activation energy of J d is lower than the effective bandgap of the blends, by ca. 0.3 to 0.5 eV, but higher than expected for mid‐gap states. Ultra‐sensitive sub‐bandgap photocurrent spectroscopy reveals that the minimum photon energy for optical charge generation in OPDs correlates with the dark current thermal activation energy. The dark current in OPDs is attributed to thermal charge generation at the donor‐acceptor interface mediated by intra‐gap states near the band edges.