Synthesis and Structure of a Copper-Based Functional Network for Efficient Organic Dye Adsorption

作者：Quanzhong Wang, Hui Wang, Xin Hu, Zhiming Fan, Yingyue Wang, Pengtao Ma, Jingyang Niu, Jingping Wang · 发表于：Inorganic Chemistry · 年份：2022 · DOI：10.1021/acs.inorgchem.2c02817 · 被引用次数：19 · 研究领域：Metal-Organic Frameworks: Synthesis and Applications、Polyoxometalates: Synthesis and Applications、Adsorption and biosorption for pollutant removal

In the work, by incorporating polyoxometalates (POMs) into a copper(II)-based network, a novel three-dimensional (3D) porous framework, [Cu 17 Cl 3 (trz) 12 ]H 3 [GaW 12 O 40 ]·9H 2 O ( Cu-GaW-TRZ ), was successfully prepared and explored for the adsorption of dyes. The adsorption capacity of Cu-GaW-TRZ was calculated as 13.11 mg/g, and the dye adsorption rate equaled 96.2% for the adsorption of methylene blue (MB). Furthermore, this recyclable adsorbent is stable enough without obvious loss of adsorption capacity for at least five runs. Meanwhile, the structure of the macropores is suitable for the entry of large molecular dyes, and [GaW 12 O 40 ] 5– also can achieve efficient adsorption for cationic dyes. The results displayed a pseudo-second-order kinetic model and were well matched for MB adsorption onto Cu-GaW-TRZ . The free energy, entropy, and enthalpy of the thermodynamic parameters for the adsorption of MB were calculated, which revealed that the adsorption process was befitting for the adsorption of MB.