High entropy oxide (Co,Cu,Mg,Ni,Zn)O exhibits grain size dependent room temperature deformation

作者：Xin Wang, Justin Cortez, Alexander D. Dupuy, Julie M. Schoenung, William J. Bowman · 发表于：Materials Research Letters · 年份：2022 · DOI：10.1080/21663831.2022.2135409 · 被引用次数：25 · 研究领域：High Entropy Alloys Studies、High-Temperature Coating Behaviors、Advanced materials and composites

Despite their vast composition space and promising properties, little is known about the fundamental mechanical behavior of high entropy oxides (HEOs). Here we provide experimental evidence of the nanoscale origin of room temperature deformation in (Co,Cu,Mg,Ni,Zn)O HEOs with different grain sizes. We find that micron-grain (Co,Cu,Mg,Ni,Zn)O deforms predominately through extensive 12<110>{1–10} dislocation slip manifesting as discrete slip bands. Nano-grain (Co,Cu,Mg,Ni,Zn)O, in addition to moderate dislocation slip activity, deforms through grain boundary sliding and intergranular cracking. The significant dislocation-mediated deformation and grain size dependent behavior demonstrates that HEOs have the potential for diverse and highly tailorable mechanical behavior.