High-efficiency electrosynthesis of urea over bacterial cellulose regulated Pd–Cu bimetallic catalyst

作者：Shengbo Zhang, Jing Geng, Zhong Zhao, Meng Jin, Wenyi Li, Yixing Ye, Ke Li, Guozhong Wang, Yunxia Zhang, Huajie Yin, Haimin Zhang, Huijun Zhao · 发表于：EES Catalysis · 年份：2022 · DOI：10.1039/d2ey00038e · 被引用次数：145 · 研究领域：Ammonia Synthesis and Nitrogen Reduction、Caching and Content Delivery、CO2 Reduction Techniques and Catalysts

PdCu/CBC exhibited a remarkable R urea of 763.8 ± 42.8 μg h −1 mg cat. −1 at −0.50 V ( vs. RHE) and an exceptional FE of 69.1 ± 3.8% at −0.40 V ( vs. RHE). Taking advantage of operando spectroscopy characterization, the C–N coupling mechanism was verified.