Electrochemical Oxidative C(sp2)–H Amination of Aldehyde Hydrazones with Azoles

作者：Zhi-Mei Fu, Jianshan Ye, Jing‐Mei Huang · 发表于：Organic Letters · 年份：2022 · DOI：10.1021/acs.orglett.2c01782 · 被引用次数：32 · 研究领域：Synthesis and Catalytic Reactions、Catalytic C–H Functionalization Methods、Radical Photochemical Reactions

)-H amination of aldehyde hydrazones with azoles has been developed. This reaction proceeds under exogenous metal-, catalyst-, and oxidant-free conditions to provide aminated hydrazone derivatives in good to excellent yields. This strategy applies to both aromatic and aliphatic aldehyde hydrazones and tolerates a broad range of functional groups.