Electrocatalytic Removal of Low-Concentration Uranium Using TiO 2 Nanotube Arrays/Ti Mesh Electrodes

作者：Leiming Lin, Tian Liu, Yukang Qie, Wenbin Liu, Ying Meng, Qingke Yuan, Fubo Luan · 发表于：Environmental Science & Technology · 年份：2022 · DOI：10.1021/acs.est.2c02632 · 被引用次数：90 · 研究领域：Radioactive element chemistry and processing、Electrochemical Analysis and Applications、Extraction and Separation Processes

Groundwater containing naturally occurring uranium is a conventional drinking water source in many countries. Removal of low concentrations of uranium complexes in groundwater is a challenging task. Here, we demonstrated that the TiO 2 nanotube arrays/Ti (TNTAs/Ti) mesh electrode could break through the concentration limit and efficiently remove low concentrations of uranium complexes from both simulated and real groundwater. U(VI) complexes in groundwater were electro-reduced to UO 2 and deposited on the TNTAs/Ti mesh electrode surface. The adsorption rate and electron transfer rate of the anatase TNTAs/Ti mesh electrode were twice that of the rutile TNTAs/Ti mesh electrode. Therefore, the anatase TNTAs/Ti mesh electrode exhibited excellent electrocatalytic activity toward the electrochemical removal of U(VI), which could work at a higher potential and significantly reduce the energy consumption of U(VI) removal. The U(VI) adsorption capacity on the anatase TNTAs/Ti mesh electrode was limited due to the low U(VI) concentration. However, the anatase TNTAs/Ti mesh electrode displayed a huge U(VI) removal capacity using the electroreduction method, where adsorption and reduction of U(VI) were mutually promoted and induced continuous accumulation of UO 2 on the electrode. The accumulated UO 2 can be easily recovered in dilute HNO 3, and the electrode can be used repeatedly.