Construction of the Skeleton of Lucidumone

作者：Shiqiang Ma, Zhen Li, Peng-Fei Yu, Hongliang Shi, Hesi Yang, Jiuzhou Yi, Zheng Zhang, Xiaoguang Duan, Xingang Xie, Xuegong She · 发表于：Organic Letters · 年份：2022 · DOI：10.1021/acs.orglett.2c02023 · 被引用次数：19 · 研究领域：Bioactive Natural Diterpenoids Research、Chemical synthesis and alkaloids、Plant-based Medicinal Research

The skeleton of lucidumone was constructed through oxidative dearomatization/intramolecular Diels-Alder reaction, Cu-mediated remote C-H hydroxylation, allyl oxidation, acid-promoted dynamic kinetic resolution cyclization, and benzylic oxidation.