A Molecular “ A ‐Type” Tangled Metallocube

作者：Lili Ma, Yang Li, Xin Li, Le Zhang, Li‐Ying Sun, Ying‐Feng Han · 发表于：Angewandte Chemie International Edition · 年份：2022 · DOI：10.1002/anie.202208376 · 被引用次数：33 · 研究领域：Supramolecular Chemistry and Complexes、Metal-Organic Frameworks: Synthesis and Applications、Organometallic Complex Synthesis and Catalysis

Abstract Tangled cubes feature the topology of typical Platonic cubes, with their “faces” traversed by edges in different ways. This study generates an “ A ‐type” tangled metallocube from the reaction of binuclear gold‐NHC complex and H 2 S. The tangled cube topology was validated by multinuclear nuclear magnetic resonance (NMR) spectroscopy, high‐resolution electrospray‐ionization (HR‐ESI) mass spectrometry, and single‐crystal X‐ray diffraction analysis. This study offers a simple and effective approach to designing and fabricating new, topologically unique molecular structures.