Viologen-Based Cationic Metal–Organic Framework for Antibiotics Detection and MnO 4 – Removal in Water

作者：Xin Li, Shi Zhang, Lin Zhang, Yan Yang, Kai Zhang, Yuchen Cai, Ying Xu, Yanli Gai, Kecai Xiong · 发表于：Crystal Growth & Design · 年份：2022 · DOI：10.1021/acs.cgd.2c00170 · 被引用次数：36 · 研究领域：Metal-Organic Frameworks: Synthesis and Applications、Molecular Sensors and Ion Detection、Advanced Nanomaterials in Catalysis

A novel Eu(III)-based cationic metal–organic framework (Eu-CMOF), formulated as [Eu(bcbp)(tdc)(H 2 O) 3 ]·Cl·5H 2 O (H 2 bcbpCl 2 = 1,1′-bis(4-carboxyphenyl)-(4,4′-bipyridinium) dichloride, H 2 tdc = 2,5-thiophenedicarboxylic acid), has been solvothermally synthesized. Eu-CMOF displays a four-fold interpenetrating three-dimensional cationic diamondoid network, in which the positive charges of the framework are derived from the bipyridinium moiety of the bcbp ligand. Notably, Eu-CMOF exhibits a good sensing ability to nitrofurantoin and nitrofurazone in aqueous solution with high selectivity and a low limit of detection. And the quenching coefficient and mechanism have also been further investigated. Meanwhile, Eu-CMOF also possesses high uptake kinetics and adsorption capacity for MnO 4 –, which is mainly attributed to the cationic framework, as well as the decentralized distribution of the positive charge.