Cage‐Ligand Strategy for the Construction of Zr 4 (embonate) 6 –Based MOFs with Third‐Order Nonlinear‐Optical Properties

作者：Qian Teng, Yan‐Ping He, Guang‐Hui Chen, Shumei Chen · 发表于：Chinese Journal of Chemistry · 年份：2022 · DOI：10.1002/cjoc.202200218 · 被引用次数：13 · 研究领域：Magnetism in coordination complexes、Nonlinear Optical Materials Research、Metal-Organic Frameworks: Synthesis and Applications

Comprehensive Summary Herein, we demonstrate a very useful strategy to construct cage‐based metal‐organic frameworks (MOFs) with third‐order nonlinear‐optical properties. More specifically, by employing the Zr 4 L 6 (L = embonate) cages to assembly with N‐contained ligands and Mn 2+ /Zn 2+ ions, four Zr 4 L 6 ‐cage‐based MOFs have been synthesized and structurally characterized. Among them, a 3D framework with strong aromatic π − π stacking force exhibits a good optical limiting effect.