Trinuclear anionic gold clusters bridged by dialkylsilylene and dialkylgermylene

作者：Yinhuan Li, Guorong Zhen, Lu Huang, Rong Zhang, Liliang Wang, Fan Qi, Mitsuo Kira, Zhifang Li · 发表于：Chemical Communications · 年份：2022 · DOI：10.1039/d2cc02054h · 被引用次数：8 · 研究领域：Nanocluster Synthesis and Applications、Organometallic Complex Synthesis and Catalysis、Molecular Junctions and Nanostructures

While the chemistry of gold clusters has been developed rapidly, the knowledge of trinuclear gold clusters with low-valent gold remains scarce. Herein, we report the synthesis, structural characterization, and density functional theory (DFT) calculations of trinuclear anionic gold clusters 3a and 3b ligated by dialkylsilylene (1a) and dialkylgermylene (1b), respectively.